The title complex [(C12H8N2)2Bi(O2NO)3] was synthesized by reaction of 1,10-phenanthroline (phen) and Bi(NO3)3·5H2O. The structure of the complex was characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. An advanced solution-reaction isoperibol microcalorimeter was applied to determine the standard molar enthalpies of formation at 298.15 K of the complex and Bi(NO3)3·5H2O, giving –(798.92 ± 5.99) and –(1986.87 ± 0.20) kJ mol−1, respectively. The biological effect of the complex was evaluated by microcalorimetry on the growth of Schizosaccharomyces pombe (S. pombe). According to thermogenic curves, the corresponding thermokinetics and thermodynamic parameters were derived. The complex had good bioactivity on the growth metabolism of S. pombe, with the value of IC50 being 2.8 × 10−5 mol L−1.
Journal of Solid State Electrochemistry - A hydrophilic polypyrrole/tellurium (PPy/Te) nanocomposite was synthesized by a facile approach in which H2TeO3 was used as the oxidizing agent of pyrrole... 相似文献
Recently, we developed methods to stabilize peptides into various secondary structures, including α‐helix, type III turn and β‐hairpin via proper thioether based macrocyclization. These conformationally constrained peptidomimetics confer enhanced biophysical properties and provide a valuable avenue towards clinically‐relevant therapeutic molecules. In this personal account, thioether‐derived macrocyclization methods developed by our group for stabilization of α‐helix, type‐III β turn and β‐hairpin conformations are discussed. 相似文献
In this paper, we investigate a Vector‐Borne disease model with nonlinear incidence rate and 2 delays: One is the incubation period in the vectors and the other is the incubation period in the host. Under the biologically motivated assumptions, we show that the global dynamics are completely determined by the basic reproduction number R0. The disease‐free equilibrium is globally asymptotically stable if R0≤1; when R0>1, the system is uniformly persistent, and there exists a unique endemic equilibrium that is globally asymptotically. Numerical simulations are conducted to illustrate the theoretical results. 相似文献
Assume that a quadratic matrix-valued function \(\psi (X) = Q - X^{\prime }PX\) is given and let \(\mathcal{S} = \left\{ X\in {\mathbb R}^{n \times m} \, | \, \mathrm{trace}[\,(AX - B)^{\prime }(AX - B)\,] = \min \right\} \) be the set of all least-squares solutions of the linear matrix equation \(AX = B\). In this paper, we first establish explicit formulas for calculating the maximum and minimum ranks and inertias of \(\psi (X)\) subject to \(X \in {\mathcal S}\), and then derive from the formulas the analytic solutions of the two optimization problems \(\psi (X) =\max \) and \(\psi (X)= \min \) subject to \(X \in \mathcal{S}\) in the Löwner partial ordering. As applications, we present a variety of results on equalities and inequalities of the ordinary least squares estimators of unknown parameter vectors in general linear models. 相似文献
Let {Xi = (X1,i,...,Xm,i)?, i ≥ 1} be a sequence of independent and identically distributed nonnegative m-dimensional random vectors. The univariate marginal distributions of these vectors have consistently varying tails and finite means. Here, the components of X1 are allowed to be generally dependent. Moreover, let N(·) be a nonnegative integer-valued process, independent of the sequence {Xi, i ≥ 1}. Under several mild assumptions, precise large deviations for Sn = Σi=1nXi and SN(t) = Σi=1N(t)Xi are investigated. Meanwhile, some simulation examples are also given to illustrate the results. 相似文献
Poly(1,2-dithiolane)s are a family of intrinsically recyclable polymers due to their dynamic covalent disulfide linkages. Despite the common use of thiolate-initiated anionic ring-opening polymerization (ROP) under basic condition, cationic ROP is still not exploited. Here we report that disulfide bond can act as a proton acceptor, being protonated by acids to form sulfonium cations, which can efficiently initiate the ROP of 1,2-dithiolanes and result in high-molecular-weight (over 1000 kDa) poly(disulfide)s. The reaction can be triggered by adding catalytic amounts of acids and non-coordinating anion salts, and completed in few minutes at room temperature. The acidic conditions allow the applicability for acidic monomers. Importantly, the reaction condition can be under open air without inert protection, enabling the nearly quantitative chemical recycling from bulk materials to original monomers. 相似文献
The utilization of carbon resources stored in plastic polymers through chemical recycling and upcycling is a promising approach for mitigating plastic waste. However, most current methods for upcycling suffer from limited selectivity towards a specific valuable product, particularly when attempting full conversion of the plastic. We present a highly selective reaction route for transforming polylactic acid (PLA) into 1,2-propanediol utilizing a Zn-modified Cu catalyst. This reaction exhibits excellent reactivity (0.65 g gcat−1 h−1) and selectivity (99.5 %) towards 1,2-propanediol, and most importantly, can be performed in a solvent-free mode. Significantly, the overall solvent-free reaction is an atom-economical reaction with all the atoms in reactants (PLA and H2) fixed into the final product (1,2-propanediol), eliminating the need for a separation process. This method provides an innovative and economically viable solution for upgrading polyesters to produce high-purity products under mild conditions with optimal atom utilization. 相似文献